Efficient synthesis of trisphenols using reduced sulfonated graphene nanocatalyst under solvent free conditions

Iranian Journal of Catalysis

مقاله 38، دوره 6، Issue 3- Special issue: Nanocatalysis، آبان 2016، صفحه 297-304   

نوع مقاله: Articles

نویسندگان

Samaneh Behravesh^{* 1، 2}؛ Reza Fareghi-Alamdari³؛ Rashid Badri^{1، 2}

¹Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran.

²Department of Chemistry, Science and Research Branch, Islamic Azad University, Iran.

³Department of Chemistry and Chemical Engineering, Malek-Ashtar University of Technology, Tehran 167653454, I.R. Iran.

چکیده

This study reports a new methodology for the efficient synthesis of trisphenol compounds using the reaction of 2,6-bis(hydroxymethyl) phenols with phenols under heterogeneous conditions. A sulfonated reduced graphene oxide (RGO-SO₃H) nanocatalyst was used to promote the reaction under solvent-free conditions. A range of trisphenol compounds were produced in the presence of this catalyst system in good to excellent yields. In the presence of this catalyst system, a less amount of phenol is required, which improves the environment through its capability in synthesis of trisphenols. The RGO-SO₃H catalyst was reusable at least for 8 times in this process without a significant decrease in its catalytic activity.

کلیدواژه‌ها

Trisphenol؛ 2؛ 6-bis(hydroxymethyl) phenols؛ Sulfonated reduced graphene oxide؛ Solvent-free conditions

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