Synthesis of 4-(trifluoromethyl) coumarins using nano sulfated-titania as solid acid catalyst under solvent-free conditions

Iranian Journal of Catalysis

مقاله 3، دوره 6، شماره 5، اسفند 2016، صفحه 423-430   

نوع مقاله: Articles

نویسندگان

Mona Hosseini-Sarvari^* ؛ Sepideh Najafvand-Derikvandi

Department of Chemistry, Shiraz University, Shiraz 71454, I.R. Iran.

چکیده

Nano sulfated titania was tested as solid acid heterogeneous catalyst for the synthesis of 4-(Trifluoromethyl) coumarin and coumarin derivatives under solvent-free condition. Factorial design evidenced a positive effect of reaction temperature, amount of catalyst, and solvents.  This nano-sized sulfated titania has been prepared by a sol-gel hydrothermal process. The prepared sulfated titania showed high catalytic activity in the synthesis of 4-(Trifluoromethyl) coumarin and coumarin derivatives. This method is of great value because of its environmentally benign character, easy handling, high yields, convenient operation, and green. FT-IR studies show that the catalyst can be reused for acylation without loss of catalytic activity.

کلیدواژه‌ها

Nano sulfated-titania؛ Coumarins؛ Pechmann reaction؛ Solvent-free condition

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