Promoting effects of calcium on the performance of Cu-MgO catalyst in hydrogenation of furfuraldehyde

Iranian Journal of Catalysis

مقاله 7، دوره 7، شماره 1، خرداد 2017، صفحه 53-59   

نوع مقاله: Articles

نویسندگان

Vahid Farzaneh^{1، 2}؛ Samira Shirvani^{1، 2}؛ Samahe Sadjadi^{1، 3}؛ Mohammad Ghashghaee^{* 1، 2}

¹Biomass Conversion Science and Technology (BCST) Division, Iran Polymer and Petrochemical Institute, P.O. Box 14975-115, Tehran, Iran.

²Faculty of Petrochemicals, Iran Polymer and Petrochemical Institute, P.O. Box 14975-112, Tehran, Iran.

³Gas Conversion Department, Faculty of Petrochemicals, Iran Polymer and Petrochemical Institute, P.O. Box 14975-112, Tehran, Iran.

چکیده

In the present study, the effects of calcium doping on the performance of the co-precipitated Cu-MgO catalysts prepared with different calcium loadings in the selective hydrogenation of furfuraldehyde were investigated. The results proved that the addition of this promoter had a remarkable impact on the catalytic performance. The conversion of furfuraldehyde enhanced up to 83% and the furfuryl alcohol selectivity remained above 96% over the run length on the promoted Cu-Ca-MgO catalyst. However, the conversion level decreased to 60% after 240 min of operation period which was still superior with respect to the negligible conversion with the non-promoted Cu-MgO catalyst.
 

کلیدواژه‌ها

Hydrogenation؛ Furfuraldehyde؛ Furfuryl alcohol؛ Cu-MgO؛ Calcium promoter؛ Biomonomer؛ Heterogeneous catalyst

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