Co3O4 nanoparticles as a robust and recoverable catalyst for one-pot synthesis of polyhydroquinolines and tetrahydrobenzopyrans

Iranian Journal of Catalysis

مقاله 10، دوره 7، شماره 1، خرداد 2017، صفحه 75-83   

نوع مقاله: Articles

نویسندگان

Mohammad Ali Ghasemzadeh^* ؛ Zahra Elyasi

Department of Chemistry, Qom Branch, Islamic Azad University, Qom, P.O. Box 364/37185. I.R. Iran.

چکیده

This study introduces a green and efficient method for preparation of biologically-active substituted 4H-pyrans using the one-pot three-component reaction of aromatic aldehydes, dimedone and malononitrile in the presence of cobalt oxide nanoparticles. Co₃O₄ nanoparticles were used as an efficient catalyst for the synthesis of polyhydroquinoline derivatives by the reaction of aromatic aldehydes, ethyl acetoacetate, dimedone and ammonium acetate. The preparation and use of Co₃O₄ as a powerful and reusable nanocatalyst under solvent-free conditions is described. The catalyst was characterized by spectral techniques including XRD, FE-SEM, FT-IR, VSM, EDX and TEM analysis. This method offers the advantages of high yield, short reaction time, comfortable work-up and reusability of the catalyst.

کلیدواژه‌ها

One-pot؛ nanocatalyst؛ Tetrahydrobenzopyran؛ Polyhydroquinoline؛ Solvent-free؛ Co3O4

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