Tungstophosphoric acid embedded magnetic chitosan as a green catalyst for the synthesis of N-cyclohexyl-3-aryl quinoxaline-2-amines

Iranian Journal of Catalysis

مقاله 3، دوره 7، شماره 3، آذر 2017، صفحه 193-199   

نوع مقاله: Articles

نویسندگان

Ali Ayati¹؛ Mansoureh Daraie²؛ Majid M. Heravi^{* 2}؛ Bahareh Tanhaei¹

¹Department of Chemical Engineering, Quchan University of Advanced Technology, Quchan, Iran.

²Department of Chemistry, School of Sciences, Alzahra University, Vanak, Tehran, Iran.

چکیده

In the present study, a novel catalyst was well designed by incorporating the tungstophosphoric acid into the magnetic chitosan, as highly stable composite, in which the iron oxides were used the strong super-magnetic core. The prepared composite was characterized by several methods, including FTIR, XRD, SEM, TEM and EDS and its catalytic activity was examined in a facile, green and highly efficient one-pot reaction for the synthesis of N-cyclohexyl-3-aryl-quinoxaline-2-amines with o-phenylenediamine, benzaldehyde and cyclohexyl isocyanide in water, under reflux conditions. This heterogeneous catalytic system was separated easily by an external magnet and was reused at least in four runs without pre-activation and appreciable loss in its activity.

کلیدواژه‌ها

Magnetic Chitosan؛ Heteropolyacid؛ Multicomponent reactions؛ Green synthesis

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