Magnetic nanosphere [e-mail]4 promoted synthesis of 5-substituted 1H-tetrazoles

Iranian Journal of Catalysis

مقاله 4، دوره 7، شماره 3، آذر 2017، صفحه 201-205   

نوع مقاله: Articles

نویسندگان

Bi Bi Fatemeh Mirjalili^{* 1}؛ Hadise Jorsarraie¹؛ Hamidreza Akrami²

¹Department of Chemistry, College of Science, Yazd University, Yazd. P.O. Box 89195-741, Iran.

²Young Researcher and Elite Club, Yazd Branch, Islamic Azad University, Yazd, Islamic Republic of Iran.

چکیده

Tetrazoles have many interesting futures and applications in drug and energy industries. 5-Substituted 1H-tetrazoles were synthesized via [2+3] cycloaddition reaction of aryl or alkyl nitriles with sodium azide in the presence of [e-mail]₄ as catalyst in DMF under reflux conditions.  The catalyst was removed from reaction mixture by an external magnet and was reusable for many times without any appreciable loss of its activity. The [e-mail]₄ promotes synthesis of tetrazole in shorter time than other reported catalysts. The obtained tetrazoles were identified by spectroscopic and physical data such as FT-IR, ¹HNMR and melting point. Easy workup and reusability of catalyst are some advantages of this protocol.

کلیدواژه‌ها

[e-mail]4؛ 1H-tetrazoles؛ Organonitrile compounds؛ Sodium azide؛ Magnetic catalyst؛ Lewis acid catalyst

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