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Kinetics of Fe2O3-Al reaction prior to mechanochemical synthesis of Fe3Al-Al2O3 nanocomposite powder using thermal analysis | ||
Journal of Nanoanalysis | ||
مقاله 7، دوره 6، شماره 3، آذر 2019، صفحه 199-204 اصل مقاله (541.97 K) | ||
نوع مقاله: Original Research Paper | ||
شناسه دیجیتال (DOI): 10.22034/jna.2019.668031 | ||
نویسنده | ||
Mehdi Khodaei* | ||
Faculty of Materials Science and Engineering, K.N. Toosi University of Technology, Tehran, Iran | ||
چکیده | ||
The effect of ball milling on kinetics of the thermite reaction of 3Fe2O3 + 8Al powder mixture to synthesize Fe3Al-Al2O3 nanocomposite was investigated using differential thermal analysis. A model-free method was applied to the non-isothermal differential calorimetry (DSC) data to evaluate the reaction kinetics according to the Starink method. The activation energy of the thermite reaction in the Fe2O3-Al system in ball milled 3Fe2O3 + 8Al powder mixture was determined to be 97 kJ/mole, which is smaller than that for non-milled powder mixture indicating the change of reaction mechanisms. The change in the reaction mechanism could be resulted from the formation of short-circuit diffusion paths occurring in the precursors during milling. The change in the reaction mechanism of such nanostructured 3Fe2O3 + 8Al powder mixture could be reason of the formation of desired phases (Fe3Al and Al2O3), which such stoichiometric phases cannot be achieved by conventional molten state thermite reaction. | ||
کلیدواژهها | ||
Differential Scanning Calorimetry (DSC)؛ Fe3Al-Al2O3؛ Kinetics؛ Mechanochemical؛ nanocomposite | ||
آمار تعداد مشاهده مقاله: 253 تعداد دریافت فایل اصل مقاله: 525 |