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Ghobadpoor, Aysoda, Eskandari, Mohammad Mehdi, Zare, Abdolkarim, Karami, Mostafa. (1399). Novel nanomagnetic material with dimethylamino tag: a selective and recyclable catalyst for the reaction of malononitrile, aryl aldehydes and dimedone. نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 11(1), 69-75.
Aysoda Ghobadpoor; Mohammad Mehdi Eskandari; Abdolkarim Zare; Mostafa Karami. "Novel nanomagnetic material with dimethylamino tag: a selective and recyclable catalyst for the reaction of malononitrile, aryl aldehydes and dimedone". نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 11, 1, 1399, 69-75.
Ghobadpoor, Aysoda, Eskandari, Mohammad Mehdi, Zare, Abdolkarim, Karami, Mostafa. (1399). 'Novel nanomagnetic material with dimethylamino tag: a selective and recyclable catalyst for the reaction of malononitrile, aryl aldehydes and dimedone', نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 11(1), pp. 69-75.
Ghobadpoor, Aysoda, Eskandari, Mohammad Mehdi, Zare, Abdolkarim, Karami, Mostafa. Novel nanomagnetic material with dimethylamino tag: a selective and recyclable catalyst for the reaction of malononitrile, aryl aldehydes and dimedone. نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 1399; 11(1): 69-75.

Novel nanomagnetic material with dimethylamino tag: a selective and recyclable catalyst for the reaction of malononitrile, aryl aldehydes and dimedone

Iranian Journal of Catalysis
مقاله 7، دوره 11، شماره 1، خرداد 2021، صفحه 69-75    اصل مقاله (692.02 K)
نوع مقاله: Articles
نویسندگان
Aysoda Ghobadpoor1؛ Mohammad Mehdi Eskandari* 2؛ Abdolkarim Zare* 1؛ Mostafa Karami1
1Department of Chemistry, Payame Noor University, PO Box 19395-3697, Tehran, Iran.
2Nanotechnology Research Center, Research Institute of Petroleum Industry (RIPI), PO Box 1485733111, Tehran, Iran.
چکیده
A novel nanomagnetic material with a dimethylamino tag namely nano-Fe3O4@SiO2@R-NMe2 ([NFSRN]) was produced, and characterized by EDS, FT-IR, VSM, FE-SEM, XRD and TGA analyses. Then, it was applied as a highly effective and magnetically recyclable catalyst for the one-pot multi-component reaction of malononitrile, arylaldehydes and dimedone. Interestingly, in most entries, among the possible products which can be produced from the reactants, only 2-amino-tetrahydrobenzo[b]pyrans were obtained in high yields and relatively short times, and no other product was obtained.  

تازه های تحقیق
  • Preparation of a nanomagnetic material with a dimethylamino tag.
  • Full Characterization of the nanomaterial.
  • Application of the nanomaterial as a selective catalyst for an organic reaction.
  • Formation of 2-amino-tetrahydrobenzo[b]pyrans among the possible products.
کلیدواژه‌ها
Nanomagnetic catalyst؛ Nano-Fe3O4@SiO2@R-NMe2 ([NFSRN])؛ 2-Amino-tetrahydrobenzo[b]pyran؛ Multi-component reaction
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