Spectral study of interaction between Silica nanoparticles and molecules of photochromic spirocompounds in solutions

International Journal of Nano Dimension

مقاله 2، دوره 13، شماره 1، فروردین 2022، صفحه 31-39   

نوع مقاله: Reasearch Paper

شناسه دیجیتال (DOI): 10.22034/ijnd.2022.684224

نویسندگان

Valery Аlexandrovich Barachevsky^{* 1، 2}؛ Olga Vladimirovna Venidiktova¹؛ Tatyana МIkhailovna Valova²؛ Artur Аlbertovich Khuzin³؛ Airat Ramilevich Tuktarov³؛ Andrey Ivanovich Shienok⁴؛ Natalia Leonidovna Zaichenko⁴

¹Photochemistry Center FSRC "Crystallography and Photonics" of the Russian Academy of Sciences, Moscow, Russia.

²Interdepartmental Center of Analytical Research of the Russian Academy of Sciences, Moscow, Russia.

³Institute of Petrochemistry and Catalysis, Ufa FRC of the Russian, Academy of Sciences, Ufa, Russia.

⁴N. N. Semenov FRC of Chemical Physics of the Russian Academy of Sciences, Москва, Russiа.

چکیده

A comparative spectral study of water–acetonitrile systems containing photochromic spiropyran and spirooxazine derivatives in the absence and in the presence of silica nanoparticles was carried out. The photoinduced formation of proton complexes beetwen phenolic oxygen of the colored forms of spirocompounds and the surface hydroxyl groups of silica nanoparticles was established for all of the derivatives. The photoinduced proton complexes of the spiropyrans exhibit positive photochromism on the surface of silica nanoparticles. It is assumed that the previously discovered negative photochromism is due to the formation of proton complexes with not only phenolic oxygen, but also the OH group at the nitrogen atom of the indoline spiropyran moiety. These complexes can also exist in the absence of nanoparticles, because of interaction with water molecules.
A comparative spectral study of water–acetonitrile systems containing photochromic spiropyran and spirooxazine derivatives in the absence and in the presence of silica nanoparticles was carried out. The photoinduced formation of proton complexes beetwen phenolic oxygen of the colored forms of spirocompounds and the surface hydroxyl groups of silica nanoparticles was established for all of the derivatives. The photoinduced proton complexes of the spiropyrans exhibit positive photochromism on the surface of silica nanoparticles. It is assumed that the previously discovered negative photochromism is due to the formation of proton complexes with not only phenolic oxygen, but also the OH group at the nitrogen atom of the indoline spiropyran moiety. These complexes can also exist in the absence of nanoparticles, because of interaction with water molecules.

کلیدواژه‌ها

Photochromism؛ Proton Complexes؛ Silica Nanoparticles؛ Spectroscopy؛ Spirocompounds

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