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Wet air oxidation of leachate containing emulsified and solubilized hydrocarbons from crude oil-contaminated soil | ||
International Journal of Industrial Chemistry | ||
دوره 10، شماره 3، آذر 2019، صفحه 237-248 | ||
نوع مقاله: research article | ||
شناسه دیجیتال (DOI): https://doi.org/10.1007/s40090-019-0187-2 | ||
نویسندگان | ||
Ganesh Sharma1، 2؛ Kshitiz Dwivedi1، 2؛ Amit Bafana1؛ Yogesh Pakade1؛ Rajesh Biniwale* 1 | ||
1CSIR-National Environmental Engineering Research Institute (NEERI), Nehru Marg, Nagpur, 440020, India | ||
2Rashtrasant Tukadoji Maharaj Nagpur University (RTMNU), Nagpur, 440033, India | ||
چکیده | ||
The present research work is focussed on the treatment of leachate generated from crude oil-contaminated soil sites using wet air oxidation as an advanced oxidation process. The factors affecting the wet air oxidation (WAO) process, viz. temperature, pressure and time of treatment were optimized using central composite design and response surface methodology. The significant factors were optimized to maximize % COD removal from the leachate. The linear effects of pressure and temperature (p = 0.000); the square effects of pressure (p = 0.019) and time (p = 0.007) and the interaction effect of temperature–pressure (p = 0.002) were found to be significantly governing the % COD removal. The maximum COD removal of 76% was obtained at temperature = 244 °C, time = 30 min and pressure = 5 bar. Further, the biodegradability index (BOD5/COD) increased from 0.14 ± 0.007 of the untreated leachate to 0.48 ± 0.02 of the wetox-treated leachate. Moreover, the degradation of recalcitrant hydrocarbons in initial leachate by WAO treatment was confirmed using GC–MS analysis. | ||
کلیدواژهها | ||
Crude oil؛ contaminated soil · Leachate · Recalcitrant hydrocarbons · Wet air oxidation · Response surface methodology · Biodegradability index | ||
آمار تعداد مشاهده مقاله: 20 |