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Solomon, Desta, Kiflie, Zebene, Van Hulle, Stijn. (1398). Using Box–Behnken experimental design to optimize the degradation of Basic Blue 41 dye by Fenton reaction. نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 11(1), 43-53. doi: https://doi.org/10.1007/s40090-020-00201-5
Desta Solomon; Zebene Kiflie; Stijn Van Hulle. "Using Box–Behnken experimental design to optimize the degradation of Basic Blue 41 dye by Fenton reaction". نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 11, 1, 1398, 43-53. doi: https://doi.org/10.1007/s40090-020-00201-5
Solomon, Desta, Kiflie, Zebene, Van Hulle, Stijn. (1398). 'Using Box–Behnken experimental design to optimize the degradation of Basic Blue 41 dye by Fenton reaction', نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 11(1), pp. 43-53. doi: https://doi.org/10.1007/s40090-020-00201-5
Solomon, Desta, Kiflie, Zebene, Van Hulle, Stijn. Using Box–Behnken experimental design to optimize the degradation of Basic Blue 41 dye by Fenton reaction. نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 1398; 11(1): 43-53. doi: https://doi.org/10.1007/s40090-020-00201-5

Using Box–Behnken experimental design to optimize the degradation of Basic Blue 41 dye by Fenton reaction

International Journal of Industrial Chemistry
دوره 11، شماره 1، خرداد 2020، صفحه 43-53
نوع مقاله: research article
شناسه دیجیتال (DOI): https://doi.org/10.1007/s40090-020-00201-5
نویسندگان
Desta Solomon* 1؛ Zebene Kiflie1؛ Stijn Van Hulle2
1Environmental Engineering Stream, School of Chemical and Bio Engineering, Addis Ababa Institute of Technology, Addis Ababa University, Addis Ababa, Ethiopia
2Department of Green Chemistry and Technology, Gent University, Campus Kortrijk, Gent, Belgium
چکیده
Degradation of a Basic Blue 41 dye using Fenton reagent was examined at laboratory scale in batch experiments using Box–Behnken statistical experiment design. Dyestuff, hydrogen peroxide (H2O2) and ferrous ion (Fe2+) concentrations were selected as independent factors. On the other hand, color and chemical oxygen demand (COD) removal were considered as the response functions. The value of coefficient of determination (R2) for both color and chemical oxygen demand removal with values 0.98 and 0.99 shows the best agreement between predicted value and experimental values. Perturbation plots indicated that iron dosage has the most effect on both color and COD removal. Normalized plot of residuals also indicated that the models were adequate to predict for both responses. Color and COD removal increased with increasing H2O2 and Fe2+ concentrations up to a certain level. High concentrations of H2O2 and Fe2+ did not result in better removal of color and COD due to hydroxyl radical being gradually consumed by both oxidant and catalyst. Percent color removal was higher than COD removal indicating the production of colorless compounds. The second-order polynomial model revealed optimal process factor ratio. The ratio of H2O2/Fe2+/dyestuff which gives a complete color removal and 95% COD removal was found to be 1195 mg/L/90 mg/L/255 mg/L.
کلیدواژه‌ها
Box؛ Behnken design . Basic Blue 41 dye . Fenton oxidation . Color removal . Chemical oxygen demand removal
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تعداد مشاهده مقاله: 25


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